Error: sending mail server does not identify itself correctly trying to send emails from snappymail

You need to update your DNS records. Go to /etc/postfix/main.cf and look for this line and edit it

## change this with your actual mailserver domain
myhostname = mail.myprimarydomain.com
# also disable ipv6 andwhich in some cases fixes the bounce
# You must stop/start Postfix after changing this parameter
# inet_protocols = all
inet_protocols = ipv4

Likelihood its just ipv6 issue. Learn more - Postfix IPv6 Support